There are a couple of problems. If the frequencies are on steps that your scanner doesn't support, the scanner will round to the closest one. It will sound off-frequency, and there is nothing to do about it. The other thing is that a narrowband channel will have lower audio than a "regular" one. Sometimes I crank the volume to the end, and depending on the radio, it is barely enough, and the squelch tail is still very loud.
I wonder how trunktracking scanners will behave, but have not tested this. Suppose an LTR system uses (say) 453.11875 (6.25kHz steps) and you can only program 12.5kHz steps (452.1125 or 453.1250). It would be off by 6.25kHz, which would probably screw up the decoding.
Dave