zz0468 -
Your single-sentence second paragraph says it all.
ANY material between the origin of the radiator and free-space will have -some kind- of impact on the radiating system parameters. There is isotropic and ultimately real-world; there is theory and then there is in practice. This is why all antenna systems that radiate must be adjusted ("tuned"). RF engineers will dictate what type of transmission line (ladder-line, coaxial cable, hard-line cable, or waveguide) should be used for a plethora of factors under general pupose conditions, but it is the installer who will then tweek the system for the exact circumstances. Just like when a simplistic vertical CB antenna is created, such as a 102" whip, which technically should be roughly 108", but due to using stainless steel (for ridgity and durability) vs copper as this alters the "actual" length used (due to the velocity factor difference of the radiator), or using 18' of coax when using a -phased- CB antenna array, or the minimum horizontal/vertical distance between 2 omni-radiating antennas on the same frequency, or the miniumum AGL height at which some antennas should be deployed, etc. There are so many factors in deploying a radiating antenna system it can get crazy. The radome material is one of least concern or impact, unless you get down deep into the depths of QRP.
Fiberglass will be less impacted by higher levels (kW range) of RF than PVC (to the point of 'melting' or 'sag').
Fiberglass is physically much more rigid than PVC, even if the PVC has a much thicker wall ("schedule").
Fiberglass is lighter than PVC.
Fiberglass sheds water better than PVC; but will absorb water if not maintained (fully 'sealed').
Fiberglass is more resistant to atmospheric pollutants (if maintained) than PVC.
Fiberglass is less pervious (if maintained) to UV than PVC.
Yes, fiberglass is clearly a better radome material than PVC, but primarily for reasons other than radiation propagation.
Since this is a home brew antenna for the 13cm band, I'm sure 'dvp' will be making plenty of adjustments to get it just right... even to the point of not painting it with metallic paint, or allowing water to get inside the radome.