It's possible that whatever the ATC facility you're listening to has enabled cross-coupling of multiple frequencies including 121.5 and/or 243.0 in error, especially if it's most noticable at repeatable times of the day or night. That would allow "perfect" reception of any regular ATC frequencies they have coupled. Without knowing what voice switch is in use I can't take it further down the rabbit hole but that's exactly what cross-coupling is for, minus using it with guard frequencies in "normal" operation of course. In Canada our enroute, TCU, Tower and FSS facilities all have that function available to them.
Just as an aside, decades ago we had a software "map" for one sector that accidentally put 121.5 in the radio module that was assigned to a regular en route frequency until the sector's midnight shift maps were activated. If the controller didn't notice, they would be transmitting on 121.5 for minutes or longer. One member of the public even filed a formal complaint about it.