I spent a good six months last year monitoring all the fed feqs in the database for Bexar. Plus, searching the VHF and uhf fed bands. CBP is pretty quiet, mixed clear, and encrypted. Same with ATF, not much traffic. Secret Service used to do weekly radio checks in the clear and encrypted from the SA field office channel on 165.2125, but I haven't heard that in a while. Every FBI simplex or repeater I ran across was fully encrypted. DEA was the most active. Next to Border Patrol and ICE. But at times, a whole conversation would be fully encrypted. So, like everyone else is saying, it's just a gamble and timing. And a lot of them just use simplex so you have to be within a mile or so usually. I know many of the feds around here use the AARRS for task force ops.
The closest thing to daily radio traffic would be the FPS at the downtown federal building. They are mixed clear and encrypted on 410.800