Idle 772.13125 is OPP BEAT01.
my current summary is this
771.84375 RM 110.9 PL MOH 700VR1 VR Mobile Repeater 1 FMN EMS Dispatch
771.89375 RM 127.3 PL MOH 700VR2 VR Mobile Repeater 2 FMN EMS Dispatch
772.05625 RM 131.8 PL MOH 700VR3 VR Mobile Repeater 3 FMN EMS Dispatch
773.03125 RM 136.5 PL MOH 700VR5 VR Mobile Repeater x FMN EMS Dispatch
771.74375 RM 67.0 PL OPP VR01 Mobile Repeater
772.13125 RM 88.5 PL OPP BEAT01 Mobile Repeater
772.14373 RM 91.5 PL OPP BEAT02 Mobile Repeater
772.15625 RM 94.8 PL OPP BEAT03 Mobile Repeater
771.88125 RM xxx.x PL MTO unknown name
My belief is that the available 700 DVRS freq were assigned a sequential individual PL for each frequency. If so then PL tones
69.3, 71.9, 74.4, 77.0, 79.7 and 82.5 may also be OPP related DVRS or 700 simplex frequencies. K9, TRU, VIP, ERU type of use.
PL tones 100.0, 103.5 and 107.2 could be anything or unused?
PL tones 114.8, 118.8 , and 123.0 should be MOH assignments
This is only speculation on my part but it does seem to account for the lack of duplication of PL tones.