Most CB communications use AM mode though there is quite a bit of SSB activity. You would have to make sure that the radio is in AM or SSB mode in order to be heard. If you are transmitting in FM mode, you probably won't be heard.
As others have mentioned Citizens Band still has rules imposed by the FCC even though individual licenses are not required. One of those FCC rules is that transmitters must have an FCC equipment authorization for Citizens Band (FCC Part 95D). Most radios sold for use on the 10 meter amateur radio band do not have FCC equipment authorization for Citizens Band and, therefore, it would be an FCC rule violation to transmit with that radio on Citizens Band.
As others have mentioned, your amateur radio license gives you absolutely no authority to operate outside of the amateur radio bands.
Also, with a Technician license, your operating privileges below 30 MHz are limited. Holders of Technician licenses are allowed to operate between 28.0 and 28.3 MHz using CW, RTTY, and data. Technicians are also allowed to operate between 28.3 and 28.5 MHz using SSB, not FM.