If the channel numbers are something simple like 3, 5, 7 then likely no bandplan and you will have to find all the frequencies by matching up activity (spikes in the FMP24 window), with a channel. In the FMP24 window, hit the "m" key. That shows activity for the range that is visible. and is sometimes helpful for finding the voice channels. Trial and error is sometimes how it works.
I would start populating the system in the files now. There are several files needed to follow a conversation as it switches between frequencies.
DSDPlus.NETWORKS gets an entry like:
TIII, 1, "unknown TIII system"
DSDPlus.SITES would be something like:
TIII, 1, 24, "unknown 24"
TIII, 1, 25, "Local site"
TIII, 1, 26, "unknown 26"
DSDPlus.FREQUENCIES would be a bit trickier as you have unknowns. Put your frequency where 421.ABCD is, put your voice slot number where @@@@ is. Each numbered voice slot gets a line. If you have adjacent numbers such as 697 and 698, only the lower one is used.
TIII, 1, 25, ?, 421.ABCD, 0.0, 0
TIII, 1, 25, @@@@, ???.????, 0.0, 0